N-(3-Chlorophenyl)benzenesulfonamide
نویسندگان
چکیده
In the crystal structure of the title compound, C(12)H(10)ClNO(2)S, the N-H bond is trans to one of the S=O bonds. The two aromatic rings form a dihedral angle of 65.4 (1)°, compared with a value of 49.1 (1)° in N-(2-chloro-phen-yl)-benzene-sulfonamide. The mol-ecules are connected by inter-molecular N-H⋯O hydrogen bonds into chains running along the b axis.
منابع مشابه
4-Chloro-N-(3-chlorophenyl)benzenesulfonamide
In the crystal of the title compound, C(12)H(9)Cl(2)NO(2)S, the mol-ecule is twisted at the S atom with a C-SO(2)-NH-C torsion angle of -58.4 (3)°. Furthermore, the N-H bond in this segment is anti to the meta-chloro group. The dihedral angle between the aromatic rings is 77.1 (1)°. The crystal structure features inversion-related dimers linked by N-H⋯O hydrogen bonds.
متن کامل2,4-Dichloro-N-(4-chlorophenyl)benzenesulfonamide
The mol-ecule of the title compound, C(12)H(8)Cl(3)NO(2)S, is twisted at the S atom, the C-SO(2)-NH-C torsion angle being 67.8 (2)°. The dihedral angle between the two benzene rings is 65.0 (1)°. The crystal structure features inversion dimers linked by pairs of N-H⋯O hydrogen bonds.
متن کامل2,4-Dichloro-N-(3-chlorophenyl)benzenesulfonamide
In the title compound, C(12)H(8)Cl(3)NO(2)S, the conformation of the N-H bond in the C-SO(2)-NH-C segment is anti to the meta-Cl in the aniline ring. The mol-ecule is twisted at the S atom, the C-SO(2)-NH-C torsion angle being 62.3 (2)°. The dihedral angle between the two benzene rings is 69.3 (1)°. The crystal structure features inversion dimers linked by pairs of N-H⋯O hydrogen bonds.
متن کامل4-Chloro-N-(2-chlorophenyl)benzenesulfonamide
In the crystal structure of the title compound, C(12)H(9)Cl(2)NO(2)S, the N-C bond in the C-SO(2)-NH-C segment has gauche torsions with respect to the S=O bonds. The mol-ecule is twisted at the S atom with an C-SO(2)-NH-C torsion angle of 57.6 (3)°. The N-H bond is syn to the ortho-chloro group in the anilino benzene ring. The two benzene rings are tilted relative to each other by 84.7 (1)°. Th...
متن کامل2,4-Dichloro-N-(2-chlorophenyl)benzenesulfonamide
In the title compound, C(12)H(8)Cl(3)NO(2)S, the conformation of the N-H bond in the C-SO(2)-NH-C segment is syn to the ortho-Cl in the aniline ring. The dihedral angle between the two benzene rings is 74.3 (1)°. An intra-molecular N-H⋯Cl hydrogen bond occurs. In the crystal, pairs of N-H⋯O hydrogen bonds link the mol-ecules into dimers.
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عنوان ژورنال:
دوره 64 شماره
صفحات -
تاریخ انتشار 2008